Product ID:SOLVENT 111,GENERAL PURPOSE GRADE,INDUSTRIA
MSDS Date:03/01/1986
FSC:6810
NIIN:00-292-9625
MSDS Number: BLJTY

VULCAN MATERIALS CO

NO 1 METROPLEX DR
BIRMINGHAM, AL 35253
US

Emergency Phone: 415-821-5338

Info Phone: 205-877-3459

Cage: 1B637

VULCAN MATERIALS CO

530390 BIRMINGHAM, AL 35253 US

Telephone: 316-524-5751

Cage: 1B637

1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)

CAS: 123-91-1

RTECS: JG8225000

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 95.5%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and
Chronic:ACUTE-EYE:IRRITATION.SKIN:PROLONGED/REPEATED CONTACT CAN
CAUSE IRRITATION,DEFATTING,DERMATITIS.INHALATION:AT LEVELS ABOVE
1000 PPM,DIZZINESS,DROWSINESS & THROAT IRRITATION.UNCONSCIOUSNESS &
DEATH POSS IBLE AT LEVELS ABOVE 10000 PPM.INGESTION:LOW TO MODERATE
TOXICITY.ASPIRATION HAZARD.CHRONIC-LIVER TOXICITY (ANIMALS).
Effects of Overexposure:EYE IRRITATION. PROLONGED OR REPEATED CONTACT
CAN CAUSE IRRITATION, DEFATTING, DERMATITIS. INHALATION AT LEVELS
ABOVE 1000 PPM CAN CAUSE DIZZINESS, DROWSINESS & THROAT IRRITATION.
UNCONSCIOUSNESS & DE ATH POSSIBLE AT LEVELS ABOVE 10000 PPM.A
SINGLE DOSE TOXICITY IS LOW TO MODERATE BUT THERE IS ASPIRATION
HAZARD.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS.

First Aid:GET MEDICAL ATTENTION-INHALATION:REMOVE TO FRESH AIR.GIVE CPR
IF NEEDED.EYE:FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR 15
MINUTES.SKIN:WASH WITH SOAP AND WATER.A SOOTHING OINTMENT MAY BE
APPLIE D.INGESTION:DO NOT INDUCE VOMITING.CALLA PHYSICIAN
IMMEDIATELY.NOTE TO PHYSICIAN:ADRENALINE SHOULD NEVER BE GIVEN TO
PERSONS OVEREXPOSED TO 1,1,1-TRICHLOROETHANE.

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:7.5
Upper Limits:15.0
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE, OR DRY CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE
PRESSURE-DEMAND,SELF-CONTAINED RESPIRATORY PROTECTION. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:CONCENTRATED VAPORS CAN BE IGNITED BY
HIGH INTENSITY IGNITION SOURCE.HYDROCHLORIC ACID GAS AND OTHER
TOXIC AND IRRITATING GASES SUCH AS PHOSGENE MAY BE PRODUCED

Spill Release Procedures:SMALL SPILL: WIPE UP WITH ABSORBING
MATERIAL.LARGE SPILLS:REMOVE USING VACUUM TRUCK.WASH THE SPILL AREA
WITH WATER.ALL WASH WATER SHOULD BE PLACED IN A CONTAINER FOR
DISPOSAL.IF SPILL OCCURS INDOORS,T URN OFF AIR CONDITIONING AND/OR
HEATINGSYSTEM.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORAGE-STORE IN A
COOL,DRY,WELL-VENTILATED LOCATION AWAY FROM
FLAMES,ALKALIES,OXIDIZERS.
Other Precautions:VAPORS ARE HEAVIER THAN AND WILL COLLECT IN LOW
AREAS. ALUMINUM EQUIPMENT SHOULD NOT BE USED FOR STORAGE AND/OR
TRANSFER. PREVENT WATER OR MOIST AIR FROM ENTERING STORAGE
TANKS/CONTAINERS. AVOID CONT ACT WITH EYES AND SKIN.

Respiratory Protection:WHERE VAPOR CONCENTRATION EXCEEDS OR IS LIKELY
TO EXCEED 350 PPM, AN APPROVED ORGANIC VAPOR TYPE RESPIRATOR IS
ACCEPTABLE. USE NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS OR AIR LINE RESPIR ATOR, WITH FULL FACE PIECE, WHEN >
1000.
Ventilation:LOCAL EXHAUST RECOMMENDED WHEREVER MIST,SPRAY OR VAPOR MAY
BE GENERATED.
Protective Gloves:SOLVENT RESISTANT GLOVES (PVA)
Eye Protection:USE CHEMICAL SAFETY GOGGLES/FACE SHIELD
Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE
EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED. DO NOT WEAR
CONTACT LENSES.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
SMOKING OR USING TOILET FACILITIES. DO NOT BREATHE VAPORS OR MIST.
Supplemental Safety and Health
DO NOT CUT OR WELD ON EMPTY OR FULL DRUMS. CONTACT WITH ALUMINUM PARTS
IN A PRESSURIZABLE FLUID SYSTEM MAY CAUSE VIOLENT REACTIONS. DO NOT
REMOVE OR DEFACE LABEL. DO NOT REUSE DRUM WITHOUT RECYCLING O R
RECONDITIONING IN ACCORDANCE WITH ANYAPPLICABLE FEDERAL, STATE OR
LOCAL LAWS.

HCC:T4
Boiling Pt:B.P. Text:165F,74C
Vapor Pres:100
Vapor Density:4.6
Spec Gravity:1.32
Evaporation Rate & Reference:0.4 (ETHER=1)
Solubility in Water:0.07 %
Appearance and Odor:CLEAR,COLORLESS LIQUID, MILDLY SWEET ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES SUCH AS NAOH, OXIDIZERS AND REACTIVE METALS
Stability Condition to Avoid:HIGH TEMPERATURES, OPEN FLAMES, WELDING
ARCS.
Hazardous Decomposition Products:WHEN INVOLVED IN FIRE,
1,1,1-TRICHLOROETHANE EMITS HIGHLY TOXIC AND IRRITATING HYDROGEN
CHLORIDE, CL2 AND PHOSGENE FUMES

Waste Disposal Methods:RECOVERED LIQUIDS MAY BE SENT TO LICENSED
RECLAIMER OR INCINERATION FACILITY. CONTAMINATED MATERIAL MUST BE
DISPOSED OF IN A PERMITTED WASTE MANAGEMENT FACILITY. CONSULT
LOCAL, STATE OR FEDERAL DISPOS AL AUTHORITIES FOR APPROVED
PROCEDURES.

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disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.